Guachapelí vs Marabú and the Kinetic pyrolysis

Authors

  • Manuel Ángel Cantos Macías Universidad Técnica de Manabí. Manabí, Ecuador
  • Omaida Quesada González Universidad de Oriente. Santiago de Cuba, Cuba
  • Rafael Rodríguez Mcfarlanes Universidad de Oriente. Santiago de Cuba, Cuba
  • Angel Luis Brito Soubanell Centro de Energía y Refrigeración. Universidad de Oriente, Cuba
  • Abdel Casanova Gómez Centro de Investigaciones para la Industria Minero Metalúrgica, Cuba

Abstract

The uses of forest residues or bushes, such as the Marabou, as a renewable resource of energy take economic and environmental importance. This work aims to characterize the Guachapelí (Ecuadorian) and Marabou (Cuban) woods chemically and energetically and study their kinetics of pyrolytic devolatilization. For this purpose, elemental, immediate analysis, and thermal analysis techniques such as Thermogravimetric Analysis, Differential Thermogravimetric and Differential Scanning Calorimetry were performed. The study showed that the chemical characteristics of the biomasses examined explain the high values of determined higher caloric power, and justify their sustainable thermal energy utilization. The kinetic analysis of the pyrolytic decomposition of these biomasses determined the kinetic models and activation energy for each step. Besides, the combination of the Coats (Integral) and Achar (Differential) equations contributes to counteract the limitations of the model-fitting Method with respect to the kinetic model.

Keywords: wood residues, pyrolysis, kinetic, guachapelí, marabú.

Published

2017-10-06

How to Cite

Cantos Macías, M. Ángel, Quesada González, O., Rodríguez Mcfarlanes, R., Brito Soubanell, A. L., & Casanova Gómez, A. (2017). Guachapelí vs Marabú and the Kinetic pyrolysis. Revista Cubana De Química, 29(3), 362–378. Retrieved from https://cubanaquimica.uo.edu.cu/index.php/cq/article/view/2944

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