Recognition to the ion Ag + with a selective electrode “all solid stated”

Authors

  • María de los A. Arada-Pérez Universidad de Oriente
  • Yoanys Pacheco-Ramírez Universidad de Oriente
  • Leandro León-Duharte Universidad de Oriente

Abstract

Has been prepared a sensitive electrode to the silver cation for that which was used 5-(4-dimethylaminobenzylidene)rhodanine dissolved in dibutylphthalate (DBP) and immobilized in polylvinyl chloride (PVC) on a support of conductive resin. The results show that the electrode presents a lineal answer in the range from 10-2 to 10-6 mol/L with a slope of 69,90 ± 1,73 mV.dec-1 respectively in the range of time that was analyzed. The time of answer of the electrode was determined (25 s) and the selectivity coefficient was calculated for diverse ions. This study has shown for the studied ions (Cu2+, Pb2+ and Cd2+) that the value of    is in the order of 10-3 mol/L, not being strong interferents for the values obtained.

Keywords: sensor; Potentiometric sensors; Ion-selective electrode, 5-(4-dimethylamino benzylidine)rhodanine.

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Published

2016-05-26

How to Cite

Arada-Pérez, M. de los A., Pacheco-Ramírez, Y., & León-Duharte, L. (2016). Recognition to the ion Ag + with a selective electrode “all solid stated”. Revista Cubana De Química, 28(2), 660–674. Retrieved from https://cubanaquimica.uo.edu.cu/index.php/cq/article/view/1150

Issue

Vol. 28 No. 2 (2016)

Section

Artículos

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