Mecanoquímica: una visión general más allá de la Química Inorgánica
Resumen
En la última década, la mecanoquímica ha surgido como una metodología novedosa en la búsqueda de alternativas sostenibles a las vías sintéticas convencionales, basadas en disolventes. Su dominio se ha extendido más allá de la química inorgánica y metalúrgica para convertirse en una poderosa técnica en todas las áreas de la química, incluyendo la química orgánica, organometálica, supramolecular, de materiales y farmacéutica. En este trabajo se da una visión general de los avances y logros recientes de la mecanoquímica, haciendo énfasis en que la misma no es solo un medio para que los procesos químicos conocidos sean más ecológicos, sino que también es una herramienta para la obtención de nuevos compuestos, así como para el descubrimiento de procesos que no se detectan en disolución.
Palabras clave: mecanoquímica, síntesis en fase sólida, química verde.
Citas
STAPERT, D.; JOHANSEN, L. “Flint and pyrite: making fire in the Stone Age”. Antiquity.1999, 73(282), 765–777.ISSN: 0003-598X.
TAKACS, L. “Quicksilver from cinnabar: The first documented mechanochemical reaction?”, Journal of the Minerals, Metals and Materials Society. 2000, 52 (1), 12-13.ISSN: 1047-4838.
CAREY-LEA, M. “On endothermic reactions effected by mechanical force”, Philosophical Magazine. 1893, 36, 351-354.ISSN: 1478-6435.
CAREY-LEA, M. “Transformations of mechanical into chemical energy”, Philosophical Magazine. 1894, 37, 470-475.ISSN: 1478-6435.
OSTWALD, W. Lehrbuch der AllgemeinenChemie. Bd.2 Stochiometrie (Engelmann, Leipzig, 1891, 1163 S.
HORIE, K.; et al. “Definitions of Terms Relating to Reactions of Polymers and to Functional Polymeric Materials (IUPAC Recommendations 2003)”,Pure and Applied Chemistry. 2004, 76(4), 889–906.ISSN: 1365-3075.
FERNÁNDEZ-BERTRÁN, J.F. “Mechanochemistry: an overview”,Pure and Applied Chemistry. 1999, 71 (4), 581–586.ISSN:1365-3075.
GEČIAUSKAITĖ, A.A.; GARCÍA F. “Main group mechanochemistry”, Beilsteinjournal of organicchemistry. 2017, 5 (13), 2068-2077. ISSN: 1860-5397.
JAMES, S. L. et al. “Mechanochemistry: opportunities for new and cleaner synthesis”, Chemical SocietyReviews. 2012, 41, 413–447.ISSN: 0306-0012.
TAN, D.; LOOTS, L.; FRISˇCˇIC, T. “Towards medicinal mechanochemistry: evolution of milling from pharmaceutical solid form screening to the synthesis of active pharmaceutical ingredients (APIs)”, Chemical Communications.2016, 52, 7760—7781. ISSN: 1359-7345.
EGUAOGIE, O. et al. “Mechanochemistry of nucleosides, nucleotides and related materials”,Beilstein journal of organic chemistry. 2018, 14, 955–970. ISSN: 1860-5397.
BOWDEN, F.P.; Yoffe, A. “Initiation and Growth of Explosion in Liquids and Solids”. Cambridge University Press: Cambridge, 1952.
BOWDEN, F.P.; YOFFE, A. “Fast Reactions in Solids”; Butterworths: London, 1958.
THIESSEN, P.A.; MEYER, K.; HEINICKE, G. “Grundlagen Der Tribochemie”.Akademie-Verlag: Berlin, 1967.
GUTMAN, E.M. “Mechanochemistry of Metals and Protection against Corrosion”.Metallurgiya: Moscow, 1974.
SMOLYAKOV, V.K.; LAPSHIN, O.V.; BOLDYREV, V.V. “Mechanochemical Synthesis of Nanosize Products in Heterogeneous Systems: Macroscopic Kinetics”, International Journal of Self-Propagating High-Temperature Synthesis. 2008, 17(1), 20–29.ISSN: 1061-3862.
SMOLYAKOV, V.K.; LAPSHIN, O.V.; BOLDYREV, V.V. “Macroscopic Theory of Mechanochemical Synthesis in Heterogeneous Systems”, International Journal of Self-Propagating High-Temperature Synthesis. 2007, 16(1), 1–11.ISSN: 1061-3862.
DO, J.L.; FRIŠČIĆ, T. “Mechanochemistry: A Force of Synthesis”, ACSCentral Science. 2017, 3(1), 13–19.ISSN: 2374-7951.
GAFFET, E.; et al. “Some recents developments in mechanical activation and mechanosynthesis”, Journal of Materials Chemestry. 1999, 9, 305-313.ISSN: 0959-9428.
BALÁZ, P. “Mechanochemestry in nanoscience and minerals engineering”.Auflage 2008. Buch. xiii, 413 S. Hardcover. ISBN: 9783540748540.
BALÁZ, P.; et al “Mechanochemistry of sulfides: from minerals to nanocrystalline semiconductors. Experimental and Theoretical Approaches to Modern Mechanochemistry”, Research Signpost, Trivandrum, Kerala, India. 2008.
KAJDAS, C. “Mechanical Activation of Chemical Process”,Materials Sciences and Applications”. 2015, 6, 60-67. ISSN: 2153-117X.
HERNÁNDEZ, J.G.; BOLM, C. “Altering Product Selectivity by Mechanochemistry”,Journal of Organic Chemistry.2017, 82 (8), 4007-4019. ISSN: 0022-3263.
MOORES, A., “Bottom up, solid-phase syntheses of inorganic nanomaterials by mechanochemistry and aging”,Current Opinion in Green and Sustainable Chemistry. 2018, 12, 33-37. ISSN: 2452-2236 .
HALASZ, I. et al. “Real-time in situ powder X-ray diffraction monitoring of mechanochemical synthesis of pharmaceutical cocrystals”,AngewandteChemie InternationalEdition. 2013, 52, 11538–11541.ISSN: 1433-7851.
FRISˇCˇIC´, T.; et al. “Real-time and in situ monitoring of mechanochemical milling reaction”, Nature Chemistry.2013, 5, 66–73.ISSN: 1755-4330.
HALASZ, I. et al. “In situ and real-time monitoring of mechanochemical milling reactions using synchrotron X-ray diffraction”,Nature Protocols. 2013, 9, 1718–1729. ISSN: 1754-2189.
KATSENIS, A.D.; et al. “In Situ X-Ray Diffraction Monitoring of a Mechanochemical Reaction Reveals a Unique Topology Metal-Organic Framework”,Nature Communications. 2015, 6(1), 6662, ISSN: 2041-1723.
KULLA, H.; et al. “In Situ Investigations of Mechanochemical One-Pot Syntheses”,AngewandteChemie InternationalEdition. 2018, 57(20), 5930–5933.ISSN: 1433-7851.
BEILLARD, A.; MÉTRO, T.X.; BANTREIL, X.; MARTINEZ, J.; LAMATY, F. “Cu(0), O2 and Mechanical Forces: A Saving Combination for Efficient Production of Cu–NHC Complexes”,Chemical Science. 2017, 8(2), 1086–1089.ISSN: 2041-6520.
HERMANN, G. N.; BECKER, P.; BOLM, C. “MechanochemicalIridium(III)-Catalyzed C−H Bond Amidation of Benzamides with Sulfonyl Azides under Solvent-Free Conditions in a Ball Mill”,AngewandteChemie InternationalEdition. 2016, 55(11), 3781–3784.ISSN: 1433-7851.
LEE, D.; KIM, Y.; CHANG, S. “Iridium-Catalyzed Direct Arene C–H Bond Amidation with Sulfonyl- and Aryl Azides”, Journal of Organic Chemistry. 2013, 78(21), 11102–11109.ISSN:0022-3263.
TANAKA K.; TODA F. “Solvent-Free Organic Synthesis”, Chemical Reviews. 2000, 100, 1025-1074. ISSN: 0009-2665.
ALAM M.T.; MAITI S.; MAL P. “The mechanochemical synthesis of quinazolin-4(3H)-ones by controlling the reactivity of IBX”,Beilstein journal of organic chemistry.2018, 12 (14), 2396-2403. ISSN: 1860-5397.
KUMAR-ACHAR, T.; BOSE, A.; MAL, P. “Mechanochemical synthesis of small organic molecules”,Beilstein journal of organic chemistry. 2017, 13, 1907–1931. ISSN: 1860-5397.
ACHAR, TK; BOSE, A; MAL, P. “Mechanochemical synthesis of small organic molecules”,Beilstein journal of organic chemistry. 2017, 11 (13), 1907-1931. ISSN: 1860-5397.
ŠTRUKIL, V. “Mechanochemical synthesis of thioureas, ureas and guanidines”,Beilstein journal of organic chemistry. 2017, 1 (13), 1828-1849. ISSN: 1860-5397.
TAN, D.; FRIŠČIĆ, T. “Mechanochemistry for Organic Chemists: An Update”, European Journal of Organic Chemistry. 2018, 1 (10) 18–33. ISSN: 1434-193X.
ANDERSEN, J.; MACK, J. “Mechanochemistry and organic synthesis: From mystical to Practical”, Green Chemistry.2018, 20, 1435-1443. ISSN:1463-9262.
FRIŠČIĆ, T. “Supramolecular concepts and new techniques in mechanochemistry: cocrystals, cages, rotaxanes, open metal-organic frameworks”,Chemical Society Reviews. 2012, 41 (9), 3493-510. ISSN: 0306-0012.
SEVERIN, K.; et al. “Synthesis of Molecular Nanostructures by Multicomponent Condensation Reactions in a Ball Mill”,Journal of the American Chemical Society. 2009, 131, 3154−3155.ISSN: 0002-7863.
BRAGA, D.; et al. “Mechanochemical preparation of molecular and supramolecular organometallic materials and coordination networks”,Dalton Transactions. 2006, 1249–1263. ISSN: 1477-9226.
MUÑOZ-BATISTA, M.J.; RODRÍGUEZ-PADRÓN, D; PUENTE-SANTIAGO, A.R.; LUQUE, R. “Mechanochemistry: towards sustainable design of advanced nanomaterials for electrochemical energy storage and catalytic applications”,ACS Sustainable Chemistry & Engineering. 2018, 6 (8), 9530-9544.ISSN: 2168-0485.
MOTTILLO, C.; FRIŠČIĆ, T. “Advances in Solid-State Transformations of Coordination Bonds: From the Ball Mill to the Aging Chamber”,Molecules. 2017, 22 (144), 1-38. ISSN: 1420-3049.
PANEQUE, A; FERNÁNDEZ-BERTRÁN, J.; REGUERA, E; YEE-MADEIRA, Y. “Solid State Reactions of Hemin with Basic Substances: Formation of bis and Mixed Complexes”, Structural Chemistry.2003, 14 (6), 551–558.ISSN: 1040-0400.
REGUERA, E.; BALMASEDA, J.; FERNÁNDEZ-BERTRÁN, J.; PANEQUE, A; YEE-MADEIRA, Y. “Complex formation of ferric protoporphyrin IX from the reaction of hemin with ammonia and small aliphatic amines”,Transition Metal Chemistry. 2004, 29, 451–456.ISSN: 0340-4285.
PANEQUE, A; FERNÁNDEZ-BERTRÁN, J.; REGUERA, E.; YEE-MADEIRA, Y. “Characterization of Hemin Complexes with Some Amino Acids”,Synthesis And Reactivity In Inorganic And Metal-Organic Chemistry. 2003, 33 (8), 1405–1416. ISSN: 1532-2440.
RODRÍGUEZ-PADRÓN, D.; et al. “SolventlessMechanochemical Preparation of Novel Magnetic Bioconjugates”,Chemical Communications. 2017, 53(54), 7635–7637. ISSN: 1359-7345.
RODRÍGUEZ-PADRÓN, D.; et al. “Mechanochemical design of hemoglobin-functionalised magnetic nanomaterials as energy storage devices”,Journal of Materials Chemistry A. 2017, 5, 16404-16411. ISSN: 2050-7488.
DELORI, A., FRISCIC, T.; JONES, W. “The role of mechanochemistry and supramolecular design in the development of pharmaceutical materials”,CrystEngComm. 2012, 14, 2350–2362. ISSN: 1466-8033.
LEONARDI, M.; VILLACAMPA, M.; MENÉNDEZ, J.C. “Multicomponent mechanochemical synthesis”, Chemical Science. 2018, 9, 2042–2064. ISSN: 2041-6520.
HASA, D.; SCHNEIDER-RAUBER, G.; VOINOVICH, D.; JONES, W. “Cocrystal Formation through Mechanochemistry: from Neat and Liquid-Assisted Grinding to Polymer-Assisted Grinding”,AngewandteChemie InternationalEdition. 2015, 54, 1 – 6. ISSN: 1433-7851.
BRAGA, D., MAINI, L.; GREPIONI, F. “Mechanochemical preparation of cocrystals”, Chemical Society Reviews. 2013, 42, 7638–7648.ISSN: 0306-0012.
BRAGA, D.; et al. “From unexpected reactions to a new family of ionic co-crystals: the case of barbituric acid with alkali bromides and caesium iodide”,Chemical Communications. 2010, 46(41), 7715–7717.ISSN: 1359-7345.
ANDRÉ, V; et al. “Mechanosynthesis of the metallodrug bismuth subsalicylate from Bi2O3 and structure of bismuth salicylate without auxiliary organic ligands”,AngewandteChemie International Edition. 2011, 50 (34), 7858-7861.ISSN: 1433-7851.
FRISˇCˇIC, T. “Supramolecular concepts and new techniques in mechanochemistry: cocrystals, cages, rotaxanes, open metal–organic frameworks”, Chemical Society Reviews. 2012, 41, 3493–3510. ISSN: 0306-0012.
BANERJEE, M.; et al. “A simple and efficient mechanochemical route for the synthesis of 2-aryl benzothiazoles and substituted benzimidazoles”, RSC Advances.2014,4, 39606-39611.ISSN: 2046-2069.
KOSOVA, N.V.; “Mechanochemical reactions and processing of nanostructured electrode materials for lithium-ion batteries”,Materials Today: Proceedings. 2016, 3, 391-395.ISSN: 2214-7853.
MALCA, M.Y.; et al. “Mechanically activated solvent-free assembly ofultrasmall Bi2S3 nanoparticles. A novel, simple and sustainable means to access chalcogenide nanoperticle”, Chemistryof Materials. 2017, 29(18), 7766–7773.ISSN: 0897-4756.
RIGHTMIRE, N.R.; Hanusa TP. “Advances in organometallic synthesis with mechanochemical methods”,DaltonTransactions. 2016, 45 (6), 2352-62. ISSN: 1477-9226.
ANDRÉ, A.; QUARESMA, S.; FERREIRA DA SILVA, J.L; DUARTE, M.T. “Exploring mechanochemistry to turn organic bio-relevant molecules into metal-organic frameworks: a short review”, Beilstein journal of organic chemistry. 2017, 13, 2416–2427. ISSN: 1860-5397.
HERNÁNDEZ, J.G.; FRIŠČIĆ, T. “Metal-Catalyzed Organic Reactions Using Mechanochemistry”, Tetrahedron Letters. 2015, 56(29), 4253–4265, ISSN: 0040-4039.
DELORI, A.; FRISCIC, T.; JONES, W. “The role of mechanochemistry and supramolecular design in the development of pharmaceutical materials”,CrystEngComm. 2012, 14, 2350-2362. ISSN: 1466-8033.
BELDON, P.J. et al. “Rapid room-temperature synthesis of zeoliticimidazolate frameworks by using mechanochemistry”,AngewandteChemie InternationalEdition. 2010, 49, 9640–9643.ISSN: 1433-7851.
BOLDYREVA, E. “Mechanochemistry of inorganic and organic systems: what is similar, what is different?”,Chemical Society Reviews. 2013, 42, 7719–7738.ISSN: 0306-0012
KLIMAKOW, M.; et al “Mechanochemical Synthesis of Metal−Organic Frameworks: A Fast and Facile Approach toward Quantitative Yields and High Specific Surface Areas”, Chemistry of Materials. 2010, 22(18), 5216–5221, ISSN: 0897-4756.
HOWARD, J.L.; CAO, Q.; BROWNE, D.L. “Mechanochemistry as an emerging tool for molecular synthesis: what can it offer?”,Chemical Science. 2018, 9, 3080–3094. ISSN: 2041-6520.
Descargas
Publicado
Cómo citar
Número
Sección
Licencia
Esta revista proporciona un acceso abierto inmediato a su contenido, basado en el principio de que ofrecer al público un acceso libre a las investigaciones ayuda a un mayor intercambio global de conocimiento. Cada autor es responsable del contenido de cada uno de sus artículos.
