PREPARACIÓN EN MEDIO ACUOSO DE RECUBRIMIENTOS AMORFOS DE TiO2 SOBRE PARTÍCULAS DE LNMO

Autores

  • Ana Laura Díaz-Perera Instituto de Ciencia y Tecnología de Materiales, Universidad de La Habana, La Habana, Cuba
  • Carlos Ricardo Milián-Pila Instituto de Ciencia y Tecnología de Materiales, Universidad de La Habana, La Habana, Cuba
  • Manuel Ávila-Santos Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada (CICATA-Legaria), Instituto Politécnico Nacional, Ciudad de México, México
  • Yodalgis Mosqueda-Laffita Instituto de Ciencia y Tecnología de Materiales, Universidad de La Habana, La Habana, Cuba
  • Eduardo Lázaro Pérez-Cappe Instituto de Ciencia y Tecnología de Materiales, Universidad de La Habana, La Habana, Cuba

Palavras-chave:

recubrimiento superficial amorfo; LNMO; TiO2; baterías de ion litio.

Resumo

Translator        

 

 

Biografia do Autor

Ana Laura Díaz-Perera, Instituto de Ciencia y Tecnología de Materiales, Universidad de La Habana, La Habana, Cuba

Translator        

 

 

Carlos Ricardo Milián-Pila, Instituto de Ciencia y Tecnología de Materiales, Universidad de La Habana, La Habana, Cuba

Translator        

 

 

Manuel Ávila-Santos, Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada (CICATA-Legaria), Instituto Politécnico Nacional, Ciudad de México, México

Translator        

 

 

Yodalgis Mosqueda-Laffita, Instituto de Ciencia y Tecnología de Materiales, Universidad de La Habana, La Habana, Cuba

Translator        

 

 

Eduardo Lázaro Pérez-Cappe, Instituto de Ciencia y Tecnología de Materiales, Universidad de La Habana, La Habana, Cuba

Translator        

 

 

Referências

KUENZEL, M. et al. “Crystal engineering of

TMPOx-coated LiNi0. 5Mn1. 5O4 cathodes for highperformance lithium-ion batteries”. Materials Today.

, 39, 127-136.

https://doi.org/10.1016/j.mattod.2020.04.003

QURESHI, Z. A. et al. “Impact of coatings on the

electrochemical performance of LiNi0.5Mn1.5O4

cathode materials: A focused review”. Ceramics

International. 2022, 48(6), 7374-7392.

https://doi.org/10.1016/j.ceramint.2021.12.118

WU, P.; ZHANG, Y. “Enhanced Electrochemical

Performance of Zr4+ and Co3+ doped LiNi0.65Mn0.35O2

Cathode Material for Lithium Ion Batteries”. International Journal of Electrochemical Science.

, 17(6), 220646.

https://doi.org/10.20964/2022.06.48

CHEN, T. et al. “The CeF4-coated spinel LiNi0.5Mn1.5O4

with improved electrochemical performance for 5 V

lithium-ion batteries”. Journal of Materials Science:

Materials in Electronics. 2022, 33(15), 11712-11724.

https://doi.org/10.1007/s10854-022-08137-5

PILLAI, A. M. et al. “Surface engineering of

Li1.5Ni0.25Mn0.75O2.5 cathode material using TiO2

nanoparticles: An approach to improve

electrochemical performance and thermal stability”.

Journal of Alloys and Compounds. 2024 976, 173064.

https://doi.org/10.1016/j.jallcom.2023.173064

DAI, S. et al. “Enhanced high-rate cycling

performance of LiMn2O4 cathode materials by coating

nano-TiO2”. International Journal of Materials

Research. 2023, 114(1), 7-15.

https://doi.org/10.1515/ijmr-2022-0070

WAGEMAKER, M. et al. “Two phase morphology

limits lithium diffusion in TiO(2)(anatase): a (7)Li

MAS NMR study”. Journal of the American

Chemical Society. 2001, 123(46), 11454-11461.

https://doi.org/10.1021/ja0161148

MOITZHEIM, S.; DE GENDT, S.; VEREECKEN,

P. M. “Investigation of the Li-Ion Insertion

Mechanism for Amorphous and Anatase TiO2 ThinFilms”. Journal of The Electrochemical Society. 2019,

(2), A1. https://doi.org/10.1149/2.1091816jes

YILDIRIM, H.; GREELEY, J.;

SANKARANARAYANAN, S. K. “Effect of

concentration on the energetics and dynamics of Li

ion transport in anatase and amorphous TiO2”. The

Journal of Physical Chemistry C. 2011, 115(31),

-15673.

https://pubs.acs.org/doi/10.1021/jp202514j

HAO, X.; BARTLETT, B. M. “Improving the

Electrochemical Stability of the High-Voltage Li-Ion

Battery Cathode LiNi0.5Mn1.5O4 by Titanate-Based

Surface Modification”. Journal of The

Electrochemical Society . 2013, 160(5), A3162.

https://doi.org/10.1149/2.025305jes

SONG, Y. W. et al. “Surface Modification of

High Voltage Spinel LiNi0.5Mn1.5O4 Cathode Material

Manufactured via Co-precipitation”. Journal of The

Electrochemical Society . 2024, 171(5), 050558.

https://doi.org/10.1149/1945-7111/ad4e6f

FEINER, A. S.; MCEVOY, A. J.. “The Nernst

Equation”. Journal of Chemical Education. 1994,

(6), 493. https://doi.org/10.1021/ed071p493

DAKANALI, M. et al. “A New Dinuclear

Ti(IV)−Peroxo−Citrate Complex from Aqueous

Solutions. Synthetic, Structural, and Spectroscopic

Studies in Relevance to Aqueous

Titanium(IV)−Peroxo−Citrate Speciation”. Inorganic

Chemistry. 2003, 42(15), 4632-4639.

https://doi.org/10.1021/ic0343051

SAVINKINA, E. V. ET AL. “Introduction of

peroxo groups into titania: Preparation,

characterization and properties of the new peroxocontaining phase”. CrystEngComm. 2015, 17(37),

-7123. https://doi.org/10.1039/C5CE01090J

WANG, L. et al. “A comparative study of Fd-3m

and P4332 “LiNi0.5Mn1.5O4”. Solid State Ionics. 2011,

(1), 32-38.

https://doi.org/10.1016/j.ssi.2011.04.007

NAKAMOTO, K. Infrared and Raman Spectra of

Inorganic and Coordination Compounds, Part A:

Theory and Applications in Inorganic Chemistry. 6ta

Edición. New Jersey: Wiley, 2008. ISBN: 978-0-471-

-2

BICHARA, L. C. et al. “Vibrational Study and

Force Field of the Citric Acid Dimer Based on the

SQM Methodology”. Advances in Physical

Chemistry. 2011, 2011 347072.

https://doi.org/10.1155/2011/347072

WU, H.; CHAN, M.; CHAN, C. “FTIR

Characterization of Polymorphic Transformation of

Ammonium Nitrate”. Aerosol Science and

Technology. 2007, 41, 581-588.

https://doi.org/10.1080/02786820701272038

BANERJEE, S.; KUMAR, A.; DEVI, P.

“Preparation of nanoparticles of oxides by the citratenitrate process”. Journal of Thermal Analysis and

Calorimetry. 2011, 104, 859-867.

https://doi.org/10.1007/s10973-011-1525-6

ZHANG, B.; WANG, Z.; & GUO, H.. “Effect of

annealing treatment on electrochemical property of

LiNi0.5Mn1.5O4 spinel”. Transactions of Nonferrous

Metals Society of China. 2007, 17(2), 287-290.

https://doi.org/10.1016/S1003-6326(07)60086-7

ZHONG, Q. et al. “Synthesis and

Electrochemistry of LiNixMn2−xO4”. Journal of The

Electrochemical Society. 1997, 144(1), 205.

https://doi.org/10.1149/1.1837386

ADAMCZYK, A.; DŁUGOŃ, E. “The FTIR

studies of gels and thin films of Al2O3-TiO2 and

Al2O3-TiO2-SiO2 systems”. Spectrochimica Acta Part

A: Molecular and Biomolecular Spectroscopy. 2012,

, 11-17. https://doi.org/10.1016/j.saa.2011.12.018

OKUDUR, F. U. et al. “Ti surface doping of

LiNi0.5Mn1.5O4−δ positive electrodes for lithium ion

batteries”. RSC Advances. 2018, 8, 7287-7300.

https://doi.org/10.1039/C7RA12932G

BHATIA, A. et al. “Detailed redox mechanism

and self-discharge diagnostic of 4.9 V LiMn1.5Ni0.5O4

spinel cathode revealed by Raman spectroscopy”.

Journal of Materials Chemistry A. 2021, 9, (13496-

. https://doi.org/10.1039/D1TA00989C

HIROI, Z. “Inorganic structural chemistry of

titanium dioxide polymorphs”. Inorganic Chemistry.

, 61(22), 8393-8401.

https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c009

CHEN, Z. et al. “Role of surface coating on

cathode materials for lithium-ion batteries”. Journal

of Materials Chemistry. 2010, 20(36), 7606-7612.

https://doi.org/10.1039/C0JM00154F

MUNIR, S. et al. “Effect of carrier concentration

on the optical band gap of TiO2 nanoparticles”.

Materials & Design. 2016, 92, 64-72.

https://doi.org/10.1016/j.matdes.2015.12.022

DENG, J. et al. “Improving the fast discharge

performance of high-voltage LiNi0.5Mn1.5O4 spinel by

Cu2+, Al3+, Ti4+ tri-doping”. Journal of Alloys and

Compounds. 2016, 677, 18-26.

https://doi.org/10.1016/j.jallcom.2016.03.256

Publicado

2025-06-10

Como Citar

Díaz-Perera, A. L., Milián-Pila, C. R., Ávila-Santos, M., Mosqueda-Laffita, Y., & Pérez-Cappe, E. L. (2025). PREPARACIÓN EN MEDIO ACUOSO DE RECUBRIMIENTOS AMORFOS DE TiO2 SOBRE PARTÍCULAS DE LNMO. Revista Cubana De Química, 37(1), 1–14. Recuperado de https://cubanaquimica.uo.edu.cu/index.php/cq/article/view/5401

Edição

Seção

Artículos