PREPARACIÓN EN MEDIO ACUOSO DE RECUBRIMIENTOS AMORFOS DE TiO2 SOBRE PARTÍCULAS DE LNMO
Palavras-chave:
recubrimiento superficial amorfo; LNMO; TiO2; baterías de ion litio.Resumo
Translator
Referências
KUENZEL, M. et al. “Crystal engineering of
TMPOx-coated LiNi0. 5Mn1. 5O4 cathodes for highperformance lithium-ion batteries”. Materials Today.
, 39, 127-136.
https://doi.org/10.1016/j.mattod.2020.04.003
QURESHI, Z. A. et al. “Impact of coatings on the
electrochemical performance of LiNi0.5Mn1.5O4
cathode materials: A focused review”. Ceramics
International. 2022, 48(6), 7374-7392.
https://doi.org/10.1016/j.ceramint.2021.12.118
WU, P.; ZHANG, Y. “Enhanced Electrochemical
Performance of Zr4+ and Co3+ doped LiNi0.65Mn0.35O2
Cathode Material for Lithium Ion Batteries”. International Journal of Electrochemical Science.
, 17(6), 220646.
https://doi.org/10.20964/2022.06.48
CHEN, T. et al. “The CeF4-coated spinel LiNi0.5Mn1.5O4
with improved electrochemical performance for 5 V
lithium-ion batteries”. Journal of Materials Science:
Materials in Electronics. 2022, 33(15), 11712-11724.
https://doi.org/10.1007/s10854-022-08137-5
PILLAI, A. M. et al. “Surface engineering of
Li1.5Ni0.25Mn0.75O2.5 cathode material using TiO2
nanoparticles: An approach to improve
electrochemical performance and thermal stability”.
Journal of Alloys and Compounds. 2024 976, 173064.
https://doi.org/10.1016/j.jallcom.2023.173064
DAI, S. et al. “Enhanced high-rate cycling
performance of LiMn2O4 cathode materials by coating
nano-TiO2”. International Journal of Materials
Research. 2023, 114(1), 7-15.
https://doi.org/10.1515/ijmr-2022-0070
WAGEMAKER, M. et al. “Two phase morphology
limits lithium diffusion in TiO(2)(anatase): a (7)Li
MAS NMR study”. Journal of the American
Chemical Society. 2001, 123(46), 11454-11461.
https://doi.org/10.1021/ja0161148
MOITZHEIM, S.; DE GENDT, S.; VEREECKEN,
P. M. “Investigation of the Li-Ion Insertion
Mechanism for Amorphous and Anatase TiO2 ThinFilms”. Journal of The Electrochemical Society. 2019,
(2), A1. https://doi.org/10.1149/2.1091816jes
YILDIRIM, H.; GREELEY, J.;
SANKARANARAYANAN, S. K. “Effect of
concentration on the energetics and dynamics of Li
ion transport in anatase and amorphous TiO2”. The
Journal of Physical Chemistry C. 2011, 115(31),
-15673.
https://pubs.acs.org/doi/10.1021/jp202514j
HAO, X.; BARTLETT, B. M. “Improving the
Electrochemical Stability of the High-Voltage Li-Ion
Battery Cathode LiNi0.5Mn1.5O4 by Titanate-Based
Surface Modification”. Journal of The
Electrochemical Society . 2013, 160(5), A3162.
https://doi.org/10.1149/2.025305jes
SONG, Y. W. et al. “Surface Modification of
High Voltage Spinel LiNi0.5Mn1.5O4 Cathode Material
Manufactured via Co-precipitation”. Journal of The
Electrochemical Society . 2024, 171(5), 050558.
https://doi.org/10.1149/1945-7111/ad4e6f
FEINER, A. S.; MCEVOY, A. J.. “The Nernst
Equation”. Journal of Chemical Education. 1994,
(6), 493. https://doi.org/10.1021/ed071p493
DAKANALI, M. et al. “A New Dinuclear
Ti(IV)−Peroxo−Citrate Complex from Aqueous
Solutions. Synthetic, Structural, and Spectroscopic
Studies in Relevance to Aqueous
Titanium(IV)−Peroxo−Citrate Speciation”. Inorganic
Chemistry. 2003, 42(15), 4632-4639.
https://doi.org/10.1021/ic0343051
SAVINKINA, E. V. ET AL. “Introduction of
peroxo groups into titania: Preparation,
characterization and properties of the new peroxocontaining phase”. CrystEngComm. 2015, 17(37),
-7123. https://doi.org/10.1039/C5CE01090J
WANG, L. et al. “A comparative study of Fd-3m
and P4332 “LiNi0.5Mn1.5O4”. Solid State Ionics. 2011,
(1), 32-38.
https://doi.org/10.1016/j.ssi.2011.04.007
NAKAMOTO, K. Infrared and Raman Spectra of
Inorganic and Coordination Compounds, Part A:
Theory and Applications in Inorganic Chemistry. 6ta
Edición. New Jersey: Wiley, 2008. ISBN: 978-0-471-
-2
BICHARA, L. C. et al. “Vibrational Study and
Force Field of the Citric Acid Dimer Based on the
SQM Methodology”. Advances in Physical
Chemistry. 2011, 2011 347072.
https://doi.org/10.1155/2011/347072
WU, H.; CHAN, M.; CHAN, C. “FTIR
Characterization of Polymorphic Transformation of
Ammonium Nitrate”. Aerosol Science and
Technology. 2007, 41, 581-588.
https://doi.org/10.1080/02786820701272038
BANERJEE, S.; KUMAR, A.; DEVI, P.
“Preparation of nanoparticles of oxides by the citratenitrate process”. Journal of Thermal Analysis and
Calorimetry. 2011, 104, 859-867.
https://doi.org/10.1007/s10973-011-1525-6
ZHANG, B.; WANG, Z.; & GUO, H.. “Effect of
annealing treatment on electrochemical property of
LiNi0.5Mn1.5O4 spinel”. Transactions of Nonferrous
Metals Society of China. 2007, 17(2), 287-290.
https://doi.org/10.1016/S1003-6326(07)60086-7
ZHONG, Q. et al. “Synthesis and
Electrochemistry of LiNixMn2−xO4”. Journal of The
Electrochemical Society. 1997, 144(1), 205.
https://doi.org/10.1149/1.1837386
ADAMCZYK, A.; DŁUGOŃ, E. “The FTIR
studies of gels and thin films of Al2O3-TiO2 and
Al2O3-TiO2-SiO2 systems”. Spectrochimica Acta Part
A: Molecular and Biomolecular Spectroscopy. 2012,
, 11-17. https://doi.org/10.1016/j.saa.2011.12.018
OKUDUR, F. U. et al. “Ti surface doping of
LiNi0.5Mn1.5O4−δ positive electrodes for lithium ion
batteries”. RSC Advances. 2018, 8, 7287-7300.
https://doi.org/10.1039/C7RA12932G
BHATIA, A. et al. “Detailed redox mechanism
and self-discharge diagnostic of 4.9 V LiMn1.5Ni0.5O4
spinel cathode revealed by Raman spectroscopy”.
Journal of Materials Chemistry A. 2021, 9, (13496-
. https://doi.org/10.1039/D1TA00989C
HIROI, Z. “Inorganic structural chemistry of
titanium dioxide polymorphs”. Inorganic Chemistry.
, 61(22), 8393-8401.
https://pubs.acs.org/doi/10.1021/acs.inorgchem.2c009
CHEN, Z. et al. “Role of surface coating on
cathode materials for lithium-ion batteries”. Journal
of Materials Chemistry. 2010, 20(36), 7606-7612.
https://doi.org/10.1039/C0JM00154F
MUNIR, S. et al. “Effect of carrier concentration
on the optical band gap of TiO2 nanoparticles”.
Materials & Design. 2016, 92, 64-72.
https://doi.org/10.1016/j.matdes.2015.12.022
DENG, J. et al. “Improving the fast discharge
performance of high-voltage LiNi0.5Mn1.5O4 spinel by
Cu2+, Al3+, Ti4+ tri-doping”. Journal of Alloys and
Compounds. 2016, 677, 18-26.

Downloads
Publicado
Como Citar
Edição
Seção
Licença
Copyright (c) 2025 Ana Laura Díaz-Perera, Carlos Ricardo Milián-Pila, Manuel Ávila-Santos, Yodalgis Mosqueda-Laffita, Eduardo Lázaro Pérez-Cappe

Este trabalho está licenciado sob uma licença Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Esta revista oferece acesso aberto imediato ao seu conteúdo, com base no princípio de que oferecer ao público o acesso gratuito à pesquisa contribui para uma maior troca global de conhecimento.