Structural and magnetic characterization of SrM/PLA multiferroic composite
Keywords:
multiferroic composites, strontium ferrite, polylactic acid, structural and magnetic characterizationAbstract
In this work, the structural and magnetic characterization of a potentially multiferroic system based on strontium ferrite (SrM) and poly lactic acid (PLA) is reported. SrM particles, obtained by the traditional ceramic method, were embedded in a PLA ferroelectric thermoplastic polymeric matrix. The structural and magnetic study was carried out using the experimental techniques of X-ray diffraction and vibrational magnetometry, respectively. To determine the phases present in each sample, the Hanawalt method was used through the Match-3! program "Phase Identification from Powder Diffraction". The results suggest the coexistence of both phases independently. For the ceramic system the parameters of the crystal lattice vary very little from the individual phase to the composite. The magnetic properties of the system are modulated as a function of the concentrations of the constituent phases and by the nature of the energetic and magnetic interactions between them.
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2. Corral-Flores V, y otros. “Enhanced magnetoelectric effect in core-shell particulate composites”. Journal of Applied Physics. 2006, 99, (8), 1-4, ISSN: 0021-8979.
3. Bhushana, B. “Sr induced modification of structural, optical and magnetic properties in Bi(1-x) Srx FeO3 (x = 0, 0.01, 0.03, 0.05 and 0.07) multiferroic nanoparticles”. Solid State Sciences. 2010, 12, 1063-1069, ISSN: 1293-2558.
4. Scott, J. F. “Applications of magnetoelectrics”. Journal of Materials Chemistry. 2012, 22, 4567–4574, ISSN: 0959-9428.
5. Wen Nan, C. y otros. “Multiferroic magnetoelectric composites: Historical perspective, status, and future directions”. Journal of Applied Physics. 2008, (103), 1-35, ISSN: 0021-8979.
6. Sedigheh, R, Abolghasem, A. “A comparison study of polymer/cobalt ferrite nano-composites synthesized by mechanical alloying route”. Journal of Ultrafine Grained and Nanostructured Materials. 2015, 48(2), 59-67, ISSN: 2423-6845.
7. Moustafa, M.; Essraa, A.; Ahmed, A. “Recent Overviews in Functional Polymer Composites for Biomedical Applications”. Polymers, 2018, 10(739), 1-21, ISSN: 2073-4360.
8. Kruzela´k, J. y otros. “Barium and strontium ferrite-filled composites based on NBR and SBR”. Journal of Elastomers and Plastics. 2018, 51(5), 421-440, ISSN: 0095-2443.
9. Kruzela´k, J. “Investigation of strontium ferrite activity in different rubber matrices”. Journal of Elastomers and Plastics. 2015, 47(3), 277-290, ISSN: 0095-2443.
10. Nagarajan, B.; Kamkar, M.; Schoen, M. “Development and Characterization of Stable Polymer Formulations for Manufacturing Magnetic Composites”. J. Manuf. Mater. Process. 2020, 4(4), 1-18, ISSN: 2504-4494.
11. Bagheri, A y otros. “Strontium Hexa-ferrites and Polyaniline Nanocomposite: Studies of Magnetization, Coercivity, Morphology and Microwave Absorption”. J Nanostruct, 2019, 9(4), 630-638, ISSN: 2251-7871.
12. Mariño-Castellanos, P. y otros. “Study of Structural and Magnetic Properties for Hybrid Compounds of X(SrFe12O19) + (1-X) (BiFeO3)”. Engineering Science. 2020, 5(1), 5-9, ISSN: 2578-9260.
13. Masoud, E. y otros. “Polymer– spinel ferrite composite containing nickel, magnesium, and nickel– magnesium ions: Structural, magnetic, electrical, and thermal stability properties”. Adv Polym Technol. 2018, 37, 3711–3722, ISSN: 0730-6679.
14. Karamanlioglu, M., Preziosi, R., Robson, GD. “Abiotic and biotic environmental degradation of the bioplastic polymer poly(lactic acid): A review”. Polymer Degradation and Stability. 2017, 137, (2), 122-130, ISSN 0141-3910.
15. Guo, R. y otros, “Electrical and Thermal Conductivity of Polylactic Acid (PLA)-Based Biocomposites by Incorporation of Nano-Graphite Fabricated with Fused Deposition Modeling”. Polymers. 2019, 11(549), 1-19, ISSN: 2073-4360.
16. Jacobi, C.; Friedrich, T.; Lüdtke-Buzug, K. “Synthesis and Characterisation of Superparamagnetic Polylactic acid based Polymers”. International Journal on Magnetic Particle Imagen. 2017, 3(2), 1-6, ISSN: 2365-9033.
17. Mohammad Abdalhadi, D; Abbas, Z.; Fahad, A. “Controlling the Properties of OPEFB/PLA Polymer Composite by Using Fe2O3 for Microwave Applications”. Fibers and Polymers. 2019, 19 (7), 1513-1521, ISSN: 1229-9197.
18. Shinyama, K. “Mechanical and Electrical Properties of Polylactic Acid with Aliphatic-Aromatic Polyester”. Journal of Engineering. 2018, 2018, 1-7, ISSN: 2314-8063.
19. Hui, S. y otros. “Preparation and Characterization of magnetic PLA/Fe3O4-g-PLLA composite melt blown nonwoven fabric for air filtration”. Journal of Engineered Fibers and Fabrics. 2020, 15(1), 1-13, ISSN: 1558-9250.
20. Ceregatti, T.; Pecharki, P.; Pachekoski, W. “Electrical and thermal properties of PLA/CNT composite films”. Revista Materia. 2017, 22(3), ISSN 1517-7076.
21. Garlotta, D. A. “Literature Review of Poly(Lactic Acid)”. Journal of Polymers and the Environment. 2001, 9(2), 63-84, ISSN: 1566-2543.
22. Mariño-Castellanos, P. y otros. “Correlación entre la microestructura de ferritas de bario tipo-M dopadas con Al 3+ y Co 3+ y sus propiedades estructurales y magnéticas”. Revista Cubana de Química. 2016, 28(1), 325-349, ISSN 2224-5421.
23. Van Son, N. “Dispersion of nanoparticles: From organic solvents to polymer solutions”. Ultrasonics Sonochemistry. 2014, 21(1), 149-153, ISSN: 1350-4177.
24. Base de datos 20200729 de la “Crystallography Open Database” http://www.crystallography.net/cod/. Fecha de revisión: 5 de julio de 2020.
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Published
2021-10-26
How to Cite
Vega-García, A., Mariño-Castellanos, P. A., & Velázquez-Infante, J. (2021). Structural and magnetic characterization of SrM/PLA multiferroic composite. Revista Cubana De Química, 33(2), 227–249. Retrieved from https://cubanaquimica.uo.edu.cu/index.php/cq/article/view/5196
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