Caracterización estructural y magnética del compósito multiferroico SrM/PLA
Palavras-chave:
compuestos multiferroicos, hexaferrita de estroncio-M, ácido poliláctico (PLA), caracterización estructural y magnéticaResumo
En este trabajo se reporta la caracterización estructural y magnética de un sistema potencialmente multiferroico formado a base de ferrita de estroncio (SrM) y poliácido láctico (PLA). Partículas de SrM, obtenidas por el método cerámico tradicional, fueron embebidas en una matriz polimérica termoplástica ferroeléctrica de PLA. El estudio estructural y magnético fue realizado usando las técnicas experimentales de difracción de rayos X y magnetometría vibracional, respectivamente. Para la determinación de las fases presentes en cada muestra se utilizó el método de Hanawalt a través del programa Match-3, “Phase Identification from Powder Diffraction”. Los resultados sugieren la coexistencia de ambas fases de forma independiente. Para el sistema cerámico los parámetros de la red varían muy poco de la fase individual al compuesto. Las propiedades magnéticas del sistema están moduladas en función de las concentraciones de las fases constituyentes y por la naturaleza de las interacciones magnéticas entre las mismas.
Referências
1. Shu-Hong, X.; Yun-Ya, L.; Jiang-Yu, L. “Synthesis, microstructures, and magnetoelectric couplings of electrospun multiferroic nanofibers”. Front. Phys. 2012, 7 (4), 399–407. ISSN: 2095-0470.
2. Corral-Flores V, y otros. “Enhanced magnetoelectric effect in core-shell particulate composites”. Journal of Applied Physics. 2006, 99, (8), 1-4, ISSN: 0021-8979.
3. Bhushana, B. “Sr induced modification of structural, optical and magnetic properties in Bi(1-x) Srx FeO3 (x = 0, 0.01, 0.03, 0.05 and 0.07) multiferroic nanoparticles”. Solid State Sciences. 2010, 12, 1063-1069, ISSN: 1293-2558.
4. Scott, J. F. “Applications of magnetoelectrics”. Journal of Materials Chemistry. 2012, 22, 4567–4574, ISSN: 0959-9428.
5. Wen Nan, C. y otros. “Multiferroic magnetoelectric composites: Historical perspective, status, and future directions”. Journal of Applied Physics. 2008, (103), 1-35, ISSN: 0021-8979.
6. Sedigheh, R, Abolghasem, A. “A comparison study of polymer/cobalt ferrite nano-composites synthesized by mechanical alloying route”. Journal of Ultrafine Grained and Nanostructured Materials. 2015, 48(2), 59-67, ISSN: 2423-6845.
7. Moustafa, M.; Essraa, A.; Ahmed, A. “Recent Overviews in Functional Polymer Composites for Biomedical Applications”. Polymers, 2018, 10(739), 1-21, ISSN: 2073-4360.
8. Kruzela´k, J. y otros. “Barium and strontium ferrite-filled composites based on NBR and SBR”. Journal of Elastomers and Plastics. 2018, 51(5), 421-440, ISSN: 0095-2443.
9. Kruzela´k, J. “Investigation of strontium ferrite activity in different rubber matrices”. Journal of Elastomers and Plastics. 2015, 47(3), 277-290, ISSN: 0095-2443.
10. Nagarajan, B.; Kamkar, M.; Schoen, M. “Development and Characterization of Stable Polymer Formulations for Manufacturing Magnetic Composites”. J. Manuf. Mater. Process. 2020, 4(4), 1-18, ISSN: 2504-4494.
11. Bagheri, A y otros. “Strontium Hexa-ferrites and Polyaniline Nanocomposite: Studies of Magnetization, Coercivity, Morphology and Microwave Absorption”. J Nanostruct, 2019, 9(4), 630-638, ISSN: 2251-7871.
12. Mariño-Castellanos, P. y otros. “Study of Structural and Magnetic Properties for Hybrid Compounds of X(SrFe12O19) + (1-X) (BiFeO3)”. Engineering Science. 2020, 5(1), 5-9, ISSN: 2578-9260.
13. Masoud, E. y otros. “Polymer– spinel ferrite composite containing nickel, magnesium, and nickel– magnesium ions: Structural, magnetic, electrical, and thermal stability properties”. Adv Polym Technol. 2018, 37, 3711–3722, ISSN: 0730-6679.
14. Karamanlioglu, M., Preziosi, R., Robson, GD. “Abiotic and biotic environmental degradation of the bioplastic polymer poly(lactic acid): A review”. Polymer Degradation and Stability. 2017, 137, (2), 122-130, ISSN 0141-3910.
15. Guo, R. y otros, “Electrical and Thermal Conductivity of Polylactic Acid (PLA)-Based Biocomposites by Incorporation of Nano-Graphite Fabricated with Fused Deposition Modeling”. Polymers. 2019, 11(549), 1-19, ISSN: 2073-4360.
16. Jacobi, C.; Friedrich, T.; Lüdtke-Buzug, K. “Synthesis and Characterisation of Superparamagnetic Polylactic acid based Polymers”. International Journal on Magnetic Particle Imagen. 2017, 3(2), 1-6, ISSN: 2365-9033.
17. Mohammad Abdalhadi, D; Abbas, Z.; Fahad, A. “Controlling the Properties of OPEFB/PLA Polymer Composite by Using Fe2O3 for Microwave Applications”. Fibers and Polymers. 2019, 19 (7), 1513-1521, ISSN: 1229-9197.
18. Shinyama, K. “Mechanical and Electrical Properties of Polylactic Acid with Aliphatic-Aromatic Polyester”. Journal of Engineering. 2018, 2018, 1-7, ISSN: 2314-8063.
19. Hui, S. y otros. “Preparation and Characterization of magnetic PLA/Fe3O4-g-PLLA composite melt blown nonwoven fabric for air filtration”. Journal of Engineered Fibers and Fabrics. 2020, 15(1), 1-13, ISSN: 1558-9250.
20. Ceregatti, T.; Pecharki, P.; Pachekoski, W. “Electrical and thermal properties of PLA/CNT composite films”. Revista Materia. 2017, 22(3), ISSN 1517-7076.
21. Garlotta, D. A. “Literature Review of Poly(Lactic Acid)”. Journal of Polymers and the Environment. 2001, 9(2), 63-84, ISSN: 1566-2543.
22. Mariño-Castellanos, P. y otros. “Correlación entre la microestructura de ferritas de bario tipo-M dopadas con Al 3+ y Co 3+ y sus propiedades estructurales y magnéticas”. Revista Cubana de Química. 2016, 28(1), 325-349, ISSN 2224-5421.
23. Van Son, N. “Dispersion of nanoparticles: From organic solvents to polymer solutions”. Ultrasonics Sonochemistry. 2014, 21(1), 149-153, ISSN: 1350-4177.
24. Base de datos 20200729 de la “Crystallography Open Database” http://www.crystallography.net/cod/. Fecha de revisión: 5 de julio de 2020.
2. Corral-Flores V, y otros. “Enhanced magnetoelectric effect in core-shell particulate composites”. Journal of Applied Physics. 2006, 99, (8), 1-4, ISSN: 0021-8979.
3. Bhushana, B. “Sr induced modification of structural, optical and magnetic properties in Bi(1-x) Srx FeO3 (x = 0, 0.01, 0.03, 0.05 and 0.07) multiferroic nanoparticles”. Solid State Sciences. 2010, 12, 1063-1069, ISSN: 1293-2558.
4. Scott, J. F. “Applications of magnetoelectrics”. Journal of Materials Chemistry. 2012, 22, 4567–4574, ISSN: 0959-9428.
5. Wen Nan, C. y otros. “Multiferroic magnetoelectric composites: Historical perspective, status, and future directions”. Journal of Applied Physics. 2008, (103), 1-35, ISSN: 0021-8979.
6. Sedigheh, R, Abolghasem, A. “A comparison study of polymer/cobalt ferrite nano-composites synthesized by mechanical alloying route”. Journal of Ultrafine Grained and Nanostructured Materials. 2015, 48(2), 59-67, ISSN: 2423-6845.
7. Moustafa, M.; Essraa, A.; Ahmed, A. “Recent Overviews in Functional Polymer Composites for Biomedical Applications”. Polymers, 2018, 10(739), 1-21, ISSN: 2073-4360.
8. Kruzela´k, J. y otros. “Barium and strontium ferrite-filled composites based on NBR and SBR”. Journal of Elastomers and Plastics. 2018, 51(5), 421-440, ISSN: 0095-2443.
9. Kruzela´k, J. “Investigation of strontium ferrite activity in different rubber matrices”. Journal of Elastomers and Plastics. 2015, 47(3), 277-290, ISSN: 0095-2443.
10. Nagarajan, B.; Kamkar, M.; Schoen, M. “Development and Characterization of Stable Polymer Formulations for Manufacturing Magnetic Composites”. J. Manuf. Mater. Process. 2020, 4(4), 1-18, ISSN: 2504-4494.
11. Bagheri, A y otros. “Strontium Hexa-ferrites and Polyaniline Nanocomposite: Studies of Magnetization, Coercivity, Morphology and Microwave Absorption”. J Nanostruct, 2019, 9(4), 630-638, ISSN: 2251-7871.
12. Mariño-Castellanos, P. y otros. “Study of Structural and Magnetic Properties for Hybrid Compounds of X(SrFe12O19) + (1-X) (BiFeO3)”. Engineering Science. 2020, 5(1), 5-9, ISSN: 2578-9260.
13. Masoud, E. y otros. “Polymer– spinel ferrite composite containing nickel, magnesium, and nickel– magnesium ions: Structural, magnetic, electrical, and thermal stability properties”. Adv Polym Technol. 2018, 37, 3711–3722, ISSN: 0730-6679.
14. Karamanlioglu, M., Preziosi, R., Robson, GD. “Abiotic and biotic environmental degradation of the bioplastic polymer poly(lactic acid): A review”. Polymer Degradation and Stability. 2017, 137, (2), 122-130, ISSN 0141-3910.
15. Guo, R. y otros, “Electrical and Thermal Conductivity of Polylactic Acid (PLA)-Based Biocomposites by Incorporation of Nano-Graphite Fabricated with Fused Deposition Modeling”. Polymers. 2019, 11(549), 1-19, ISSN: 2073-4360.
16. Jacobi, C.; Friedrich, T.; Lüdtke-Buzug, K. “Synthesis and Characterisation of Superparamagnetic Polylactic acid based Polymers”. International Journal on Magnetic Particle Imagen. 2017, 3(2), 1-6, ISSN: 2365-9033.
17. Mohammad Abdalhadi, D; Abbas, Z.; Fahad, A. “Controlling the Properties of OPEFB/PLA Polymer Composite by Using Fe2O3 for Microwave Applications”. Fibers and Polymers. 2019, 19 (7), 1513-1521, ISSN: 1229-9197.
18. Shinyama, K. “Mechanical and Electrical Properties of Polylactic Acid with Aliphatic-Aromatic Polyester”. Journal of Engineering. 2018, 2018, 1-7, ISSN: 2314-8063.
19. Hui, S. y otros. “Preparation and Characterization of magnetic PLA/Fe3O4-g-PLLA composite melt blown nonwoven fabric for air filtration”. Journal of Engineered Fibers and Fabrics. 2020, 15(1), 1-13, ISSN: 1558-9250.
20. Ceregatti, T.; Pecharki, P.; Pachekoski, W. “Electrical and thermal properties of PLA/CNT composite films”. Revista Materia. 2017, 22(3), ISSN 1517-7076.
21. Garlotta, D. A. “Literature Review of Poly(Lactic Acid)”. Journal of Polymers and the Environment. 2001, 9(2), 63-84, ISSN: 1566-2543.
22. Mariño-Castellanos, P. y otros. “Correlación entre la microestructura de ferritas de bario tipo-M dopadas con Al 3+ y Co 3+ y sus propiedades estructurales y magnéticas”. Revista Cubana de Química. 2016, 28(1), 325-349, ISSN 2224-5421.
23. Van Son, N. “Dispersion of nanoparticles: From organic solvents to polymer solutions”. Ultrasonics Sonochemistry. 2014, 21(1), 149-153, ISSN: 1350-4177.
24. Base de datos 20200729 de la “Crystallography Open Database” http://www.crystallography.net/cod/. Fecha de revisión: 5 de julio de 2020.
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2021-10-26
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Vega-García, A., Mariño-Castellanos, P. A., & Velázquez-Infante, J. (2021). Caracterización estructural y magnética del compósito multiferroico SrM/PLA. Revista Cubana De Química, 33(2), 227–249. Recuperado de https://cubanaquimica.uo.edu.cu/index.php/cq/article/view/5196
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